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    2,4-Dioxa-λ-6-thiatetracyclo-[5.3.1.15,9. 01,5]dodecane-3,3-dione

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    Date
    2012-06-01
    Author
    Ioannou, Savvas
    Moushi, Eleni E.
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    Abstract
    The crystal structure of the title compound, C9H 12O4S, was determined in order to investigate the effect of the eclipsed O atoms on the bond length of the vicinal quaternary C atoms. The two quaternary C atoms of the noradamantane skeleton and the two O atoms to which they are connected all located essentially in the same plane (maximum deviation = 0.01 Å), resulting in an eclipsed conformation of the C - O bonds. The C - C bond of the quaternary C atoms is 1.581 (3) Å, considerably longer than the other C - C bonds of the molecule due to the stretch of the cage structure.
    URI
    https://www.scopus.com/inward/record.uri?partnerID=HzOxMe3b&scp=84862273393&origin=inward
    https://repo.euc.ac.cy/handle/123456789/1715
    DOI
    10.1107/S160053681202079X
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